Rethinking boltzmannian equilibrium
Werndl, Charlotte; and Frigg, Roman
(2015)
Rethinking boltzmannian equilibrium
Philosophy of Science, 82 (5).
pp. 1224-1235.
ISSN 0031-8248
Boltzmannian statistical mechanics partitions the phase space of a sys- tem into macro-regions, and the largest of these is identified with equilibrium. What justifies this identification? Common answers focus on Boltzmann’s combinatorial argument, the Maxwell-Boltzmann distribution, and maxi- mum entropy considerations. We argue that they fail and present a new answer. We characterise equilibrium as the macrostate in which a system spends most of its time and prove a new theorem establishing that equilib- rium thus defined corresponds to the largest macro-region. Our derivation is completely general in that it does not rely on assumptions about a system’s dynamics or internal interactions.
| Item Type | Article |
|---|---|
| Departments |
Philosophy, Logic and Scientific Method CPNSS Centre for Analysis of Time Series |
| DOI | 10.1086/683649 |
| Date Deposited | 25 Nov 2014 09:04 |
| URI | https://researchonline.lse.ac.uk/id/eprint/60250 |
Explore Further
- http://www.lse.ac.uk/cpnss/people/charlotte-werndl.aspx (Author)
- http://www.lse.ac.uk/cpnss/people/roman-frigg.aspx (Author)
- http://journal.philsci.org/ (Official URL)
ORCID: https://orcid.org/0000-0003-0812-0907